Below is a selection of the important experiments which helped to form quantum mechanics. It's presented in table form.
Rough year |
Name of the experiment |
Name of relevant physicists and
contribution |
What's the deviation compared to
classical |
Impact |
1900 |
Thermal radiation of different
frequencies emitted by a body. |
Max Planck, for putting the adhoc
solution E=nhf. |
Classical theories can account for
ends of high frequency and low frequency using two equations, Max Planck's
one equation combined them both. |
Light seems to carry energy in
quantised quantity, the origin of quantum, thought of as mathematical trick. |
1905 |
Photo electric effect |
Albert Einstien, for taking seriously
the suggestion that light is quantized. |
We expect that light can expel electron at any frequency, but reality is,
only light with high enough frequency can expel electrons. |
The beginning of taking the maths of
quantum physics seriously as stories, that light is a particle called photon. |
1913 |
Hydrogen Atomic spectra |
Niels Bohr, for explaining the spectra
lines with Bohr atomic model. |
Updated the Rutherford model of the
atom (just 2 years old then) to become Bohr model. Rutherford model has one
positive nucleus at the centre and electrons just scattered around it, Bohr
had the electron orbits around the nucleus, like a mini solar system, which
is still our popular conception of the atom, even when it has been outdated. |
Serves as a clue in the development of
quantum mechanics. It predicts angular momentum is quantised, which leads to
the Stern-Gerlach experiment. |
1922 |
Stern–Gerlach experiment |
Otto Stern and Walter Gerlach, for
discovering that spatial orientation of angular momentum is quantised. |
If atoms were classically spinning
objects, their angular momentum is expected to be random and continuously
distributed, the results should be some density distribution, but what is
observed is a discrete separation due to quantised angular momentum. |
1. Measurement changes the system
being measured in quantum mechanics. Only the spin of an object in one
direction can be known, and observing the spin in another direction destroys
the original information about the spin. 2. The results of the measurement is
probabilistic: any individual atom sent into the apparatus have equal chance
of going up or down. Unless we already know from previous measurement its
spin in the same direction. |
1961 |
Young's double-slit experiment with
electrons |
Thomas Young did it with light first in 1801, then Davisson and Germer in
1927 used electrons with crystals, finally Clauss Jönsson made the
thought experiment a reality. In 1974, Pier Giorgio Merli did it with single
electrons. |
If electrons does not have wavelike
properties like a classical ball, it would never have shown interference
patterns. The double-slit experiment is now also capable of being done with
single particles, interference still occurs. Classical expectation would not
have allowed single particle to interfere with itself. |
The double-slit experiment is still
widely used as the introduction to quantum weirdness, likely popularised by
Richard Feymann's claim that all the mysteries of the quantum is in this
experiment. Since then, it's possible to explain single particles quantum
behaviour without the mysteries. https://doi.org/10.1103/PhysRevA.98.012118 |
1982 |
Bell's Inequality Violation |
Einstein, Podolsky, Rosen, for
bringing up the EPR paradox, John Bell for formulating the paradox into a
Bell inequality, Alain Aspect for testing CHSH, a version of Bell's
inequality, B. Hensen et. al. did a loop hole free version in 2015. |
If the world behaves classically, that
is it has locality (only nearby things affect each other at most at the speed
of light), counterfactual definiteness (properties of objects exist before we
measure them), and freedom (physical possibility of determining settings on
measurement devices independently of the internal state of the physical
system being measured), then Bell's inequality cannot be violated. Quantum
entangled systems can violate Bell's inequality. Showing that one of the
three assumptions of the classical world has to be discarded. |
The world accepts the existence1999 of
quantum entanglement, this also leads to more research into fundamental
quantum questions as EPR was for a long time considered unbeneficial
fundamental question. However, on closer inspection as in with Bell's
inequality, it revealed new stuffs to us, and helped usher in the age of
quantum information technology. |
1999 |
Delayed-choice quantum eraser |
Yoon-Ho Kim et. al. for doing the
experiment, John Archibald Wheeler thought of the original thought
experiment of delayed choice. |
Quantum eraser is that one can erase
the which-way information after measuring it, thus determining the results of
interference or no interference pattern on the double slit. The delayed
choice means one can determine to erase or not after the measurement was
done. So how we describe the past depends on what happens in the future,
contrary to our intuition that the past is fully described by events
happening in the past. Note what happens is the same, just that new
information can be gained based on decisions in the future. |
This is one of the popular
counter-intuitive experiments commonly used to evaluate and test out our
intuition about quantum mechanics and its interpretations. It's frequently
used in many popular accounts of quantum physics. |
Stern–Gerlach experiment
The set up is to shoot silver atoms to
an unequal distribution (inhomogeneous) of magnetic field. As suggested by
Bohr, angular momentum is quantised. You can think of spin as a form of angular
momentum. For those who forgot what angular momentum is, it is mass times
velocity times radius of rotation for a massive body rotating around an axis.
It can be generalised to everything that rotates has angular momentum. All
particles possess this spin property, we call it intrinsic angular momentum.
That's not to say that it physically spin. Why?
Let’s assume that the electron is a small
ball, of the radius 10-19 m, corresponding to the smallest distance probed by Large
Hadron Collider. In the standard model, the electron is basically zero size, a
zero-dimensional point particle, but for the sake of imagining it spinning
around, we give it size for now. The electron has an intrinsic angular momentum
of 1/2 of reduced Planck’s
constant. Numerically that’s 5.27 x 10-35 kg m2 s-1. Moment of inertia of a
solid sphere is 0.4 MR2, for electron, that’s 3.6 x 10-69 kgm2. So
calculating the angular velocity of the electron, we divide the angular
momentum by the moment of inertia, we get 1.4 x 1031s-1.
That is the electron spins that many times per second, putting in radius of
electron to calculate the velocity at the surface of the electron as sphere, we
get 1.4 x 1012 ms-1. That’s much faster than light which is in
the order of 108 ms-1.
The smaller radius we give the electron, the higher the velocity we get. So we
cannot interpret spin as the subatomic particles physically spinning.
Silver atoms also has spin. As silver
atoms are made up of charged parts, and moving charges generates magnetic
fields, all particles made out of charged parts or has charges behave like
little magnets (magnetic dipole). And these little magnets should be deflected
by the inhomogeneous magnetic field. We use silver atoms to have neutral
electrical charge, so that we only see spin in the following experiment.
Say, if we imagine electrons, protons
etc as physically spinning (which I warned is the wrong picture), we would
expect that the magnet can point in any direction along the up-down axis. To
make it more concrete, look at the picture and take the Cartesian coordinates z
as the direction in which line 4 points at, the up or down along the screen.
y-coordinate is the direction from the source of the Silver atoms, 1 to the
screen. x-coordinate is left and right of the screen then. So the measurement
of the spin is now orientated along the z-axis, the up-down axis. If the spin
is fully pointing along up or down z direction, it will have maximum deflection
as shown on 5. If the spin has y-components, so that it can have a distribution
of values between the ups and downs of z-axis, then we would expect 4 to be the
results of the experiment. This again is the classical picture of thinking of
spin as physical rotation, so classical results are 4 on the screen.
Experimentally, the results are always
5. Never any values in between. This might look weird, and indeed is the start
of many of the weird concepts we will explore below which is fundamental in the
Copenhagen Introduction to quantum mechanics.
Some questions you might want to ask is,
do the spins have ups and downs initially (stage one), but they are snap into
up or down only via the measurement (stage two)? Or is it something else more
tricky?
Stern–Gerlach experiment: Silver atoms
travelling through an inhomogeneous magnetic field, and being deflected up or
down depending on their spin; (1) furnace, (2) beam of silver atoms, (3)
inhomogeneous magnetic field, (4) classically expected result, (5) observed
result
Photo by Tatoute - Own work, CC BY-SA
4.0, https://commons.wikimedia.org/w/index.php?curid=34095239
Further magical property is that if I
remove the screen, put another inhomogeneous magnetic field pointed along the
x-axis (henceforth called a measurement in x-axis) on the beam of atoms which
has up z-spin. (The same results happens even if I choose the down z-spin.)
Then what I have is two streams pointed left (x+) and right (x-). That's to be
expected. If I bring apply again the z-axis measurement onto any of these left
or right spins, the results split again into up and down z-axis.
If you think that this tells us that we
cannot assume that the particle remembers its previous spin, then apply another
z-axis measurement onto the up z-spin particles, they all go up as shown in the
picture below. S-G stands for Stern-Gerlach apparatus, the measurement apparatus
which is basically just the inhomogeneous magnetic field. One way to interpret
this is that depending on how you measure, measurement changes what is
measured.
Picture from Wikipedia
If you put another x-axis measurement as
the third measurement on the middle part, one for each beam, the beam which has
up x-axis (x+) will 100% go up again, and the one with down x-axis (x-) will go
100% go down again.
It seems that the rules are
a. Measurement changes the system being
measured in quantum mechanics. Only the spin of an object in one direction can
be known, and observing the spin in another direction destroys the original
information about the spin.
b. The results of the measurement is
probabilistic: any individual atom sent into the apparatus have an equal chance
of going up or down. Unless we already know from previous measurement its spin
in the same direction.
This does lead to two things which is
troubling to classical thinking. Contextuality or the answer depends on the
question. And inherent randomness. More on contextuality later, for now, we
focus on randomness. Normal randomness we have in the classical world is due to
insufficient information in the world. If we gather enough data, we can always
predict the results of coin toss or dice roll. Yet, in the quantum systems,
there seems to be no internal mechanism for them (or is there? Look out for
hidden variables interpretation), we have the maximum information from its
wavefunction (according to Copenhagen interpretation) and thus the randomness
is inherent in nature.
Some people do not like inherent
randomness, some do. Why? Classical physics is very much based on Newtonian
clockwork view of the universe. With the laws of motion in place, we had
discovered also how heat flows, how electromagnetism works, even all the way to
how spacetime and mass-energy affect each other in general relativity. One
thing is common to all of these. They are deterministic laws. That is if by
some magic, we can get all the information in the world at one slice of time
(for general relativity, it means one hypersurface), plug it into the classical
equations, we can predict all of the past and future to any arbitrary accuracy,
without anything left to chance, randomness. That's a worldview of the universe
which is deterministic, clockwork, incompatible with anything which has
intrinsic, inherent randomness.
So, some view that the main goal of
interpretation is to get back into the deterministic way of the universe. Yet,
others see this indeterminism as an advantage as it allows for free will. More
on that later. For now, let us jump on board to try to save determinism.
If we do not like intrinsic randomness,
if we insist that there is some classical way to reproduce this result, then
one fun way to think about it is that each particle has its own internal
if-then preparations. The particle instructions are: If I encounter the z
measurement, I will go up, if x, then I will go left, if z after x, then I will
go down, or else I will go up. And so on. We shall explore this in detail in
the next section on playing a quantum game, to try to use classical strategies
to simulate quantum results.
For Buddhists, here’s
a motivation to follow the quantum game analysis (it gets heavy). We believe in
cause and effect relationships. So intrinsic randomness seems to be at odds
with causal relationships. Think about it. The same atoms of silver prepared
the same way, say after it exited the z-axis, we only select the spin up z-axis
silver atoms. When we put in another cause of putting a measurement of x-axis
to it, it splits into up x and down x. Same atoms with the exact same
wavefunctions, thus same causes, same conditions of putting measurement on
x-axis, different results of up and down in x-axis. That intrinsic randomness
according to some quantum interpretations has no hidden variables beneath it.
So if we wish to recover predictability and get rid of intrinsic randomness, we
better pay attention to try to simulate the quantum case using classical
strategies to avoid intrinsic randomness.
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